TRANS-1,2-DIBROMOCYCLOHEXANE


  • CAS 7429-37-0
  • Purity 99%
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Factory Export Top Purity TRANS-1,2-DIBROMOCYCLOHEXANE 7429-37-0 In Stock

  • Molecular Formula: C6H10Br2
  • Molecular Weight: 296.045
  • Appearance/Colour: Colourless to light yellow liquid 
  • Vapor Pressure: 0.166mmHg at 25°C 
  • Melting Point: -5 °C 
  • Refractive Index: 1.551-1.553  
  • Boiling Point: 220.5 °C at 760 mmHg 
  • Flash Point: 91.5 °C 
  • PSA: 0.00000 
  • Density: 1.789 g/cm3 
  • LogP: 3.08740 

TRANS-1,2-DIBROMOCYCLOHEXANE(Cas 7429-37-0) Usage

InChI:InChI=1/C6H10Br2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4H2/t5-,6-/m0/s1

7429-37-0 Relevant articles

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Hayes et al.

, p. 4524 (1950)

-

-

White

, p. 6215,6218 (1955)

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Linear Paired Electrolysis—Realising 200 % Current Efficiency for Stoichiometric Transformations—The Electrochemical Bromination of Alkenes

Strehl, Julia,Abraham, Marvin L.,Hilt, Gerhard

supporting information, p. 9996 - 10000 (2021/03/31)

The generation of bromine by oxidation o...

Dibrominated addition and substitution of alkenes catalyzed by Mn2(CO)10

Chan, Albert S. C.,Jiang, Yi,Meng, Shanshui,Song, Xianheng,Zhang, Hong,Zou, Yong

supporting information, p. 13385 - 13388 (2021/12/17)

A practical method for the dibromination...

Green bromination method

-

Paragraph 0068-0070, (2021/06/13)

The invention discloses a green brominat...

Tandem Deoxygenation/Halogenation of N-Oxides Under Acylation Conditions: Scope and In Situ IR Spectroscopic Study

Malykhin, Roman S.,Golovanov, Ivan S.,Ioffe, Sema L.,Sukhorukov, Alexey Yu.

, p. 4139 - 4148 (2019/04/03)

Acylation of cyclic nitronates with acyl...

7429-37-0 Process route

1-bromocyclohexane
108-85-0

1-bromocyclohexane

dibromo-cyclohexane
10489-97-1

dibromo-cyclohexane

cis-1,3-dibromocyclohexane
31025-70-4

cis-1,3-dibromocyclohexane

trans-1,4-dibromocyclohexane
13618-83-2

trans-1,4-dibromocyclohexane

trans-1,2-dibromocyclohexane
7429-37-0

trans-1,2-dibromocyclohexane

Conditions
Conditions Yield
With tert.-butylhydroperoxide; Bromotrichloromethane; ferric nitrate; In pyridine; acetic acid; at 60 ℃; for 10h; Further byproducts given;
29%
16.1%
20.4%
2.9%
cis-bicyclo<2.2.0>hexane
186-04-9,72033-85-3

cis-bicyclo <2.2.0> hexane

trans-1,4-dibromocyclohexane
13618-83-2

trans-1,4-dibromocyclohexane

trans-1,2-dibromocyclohexane
7429-37-0

trans-1,2-dibromocyclohexane

cis-1-bromobicyclo<2.2.0>hexane
113555-32-1

cis-1-bromobicyclo <2.2.0> hexane

exo-2-bromobicyclo<2.2.0>hexane
113555-33-2

exo-2-bromobicyclo <2.2.0> hexane

Conditions
Conditions Yield
With tert-butylethylene; 2,2'-azobis(isobutyronitrile); N-bromobis(trimethylsilyl)amine; In benzene-d6; at 75 ℃; for 62h; Further byproducts given. Title compound not separated from byproducts;
35 % Chromat.
32 % Chromat.
5 % Chromat.
8 % Chromat.

7429-37-0 Upstream products

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    2-bromocyclocyclohexanol

  • 762-84-5
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    N-tert-butylacetamide

7429-37-0 Downstream products

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    61862-37-1

    (2-cyclohexen-1-yl)piperidine

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    trans-1,2-dimethoxycyclohexane

  • 93250-27-2
    93250-27-2

    (+/-)-trans -1.2-diethoxy-cyclohexane

  • 7145-47-3
    7145-47-3

    optically inactive 4.4'-di-(cyclohexen-(2)-yloxy)-α.α'-diethyl-trans -stilbene

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